催化作用
脚手架
兴奋剂
化学
化学工程
材料科学
组合化学
生物化学
计算机科学
光电子学
数据库
工程类
作者
Yuan Huang,Jianjun Wang,Yang Zou,Li‐Wen Jiang,Xiaolong Liu,Wenjie Jiang,Hong Liu,Jin‐Song Hu
出处
期刊:Chinese Journal of Catalysis
[China Science Publishing & Media Ltd.]
日期:2021-08-01
卷期号:42 (8): 1395-1403
被引量:52
标识
DOI:10.1016/s1872-2067(20)63739-1
摘要
There remains a challenge in designing electrocatalysts for water oxidation to create highly efficient catalytic sites for the oxygen evolution reaction (OER) while maintaining their robustness at large outputs. Herein, an etching-assisted synthesis approach was developed to integrate highly active NiFe 2 O 4 nanoparticles with a robust and active NiOOH scaffold directly on commercial stainless steel. A precise selenization strategy was then introduced to achieve selective Se doping of NiFe 2 O 4 to further enhance its intrinsic OER activity while maintaining a three-dimensional NiOOH nanosheet array as a robust scaffold for prompt mass transfer and gas evolution. The resulting NiFe 2 O 4− x Se x /NiOOH electrode exhibited superior electrocatalytic activity with low overpotentials of 153 and 259 mV to deliver benchmark current densities of 10 and 500 mA cm −2 , respectively. More importantly, the catalyst exhibited remarkable durability at a stable current output of 100 mA cm −2 for hundreds of hours. These findings may open up opportunities for exploring efficient and robust electrocatalysts for scalable hydrogen production with practical materials. The rational fabrication of selectively Se-doped NiFe 2 O 4 nanoparticles on active NiOOH nanosheet arrays enables efficient and robust OER electrocatalysts for scalable hydrogen production with commercial stainless steel.
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