Based on TRIZ Methodology Design and Preparation of a Robust Skeletal Superhydrophobic Perfluoropolysiloxane and Polyaniline/Epoxy Resin Composite Coating with Outstanding Anti-Corrosion Performance

环氧树脂 材料科学 涂层 复合材料 复合数 腐蚀 超疏水涂料 接触角 聚苯胺 聚合物 聚合
作者
Haidong Xu,Youliang Wang,Dan Zhao,Nali Chen,Lin Tan,Huixia Feng
出处
期刊:Bulletin of the Chemical Society of Japan [Oxford University Press]
卷期号:94 (10): 2390-2395 被引量:2
标识
DOI:10.1246/bcsj.20210187
摘要

Corrosion not only causes substantial economic losses, but can also threaten personal safety. Superhydrophobic polyaniline composite anti-corrosion coating (SPANC) has closely received attention due to slowing chemical and electrochemical corrosion simultaneously, but the poor mechanical properties cannot meet actual needs. In this paper, function analysis, substance-field model and standard inventive solutions in TRIZ were used to solve the poor mechanical properties of SPANC, and a robust skeletal superhydrophobic perfluoropolysiloxane and polyaniline/epoxy resin composite coating (EPAMA-NPOS) was designed and prepared. The contact angle (CA) and sliding angle (SA) of H-SiO2@POS reach 165.0° ± 1.0 and 1.7° ± 0.03, respectively, the protection efficiency of EPAMA-NPOS reaches 99.94%, in friction test, and the CA is reduced from 165.0° to 147.0° after 310 times. The EPAMA-NPOS has achieved excellent superhydrophobicity, corrosion resistance and mechanical properties. The superhydrophobic polyaniline composite anti-corrosion coating has closely received attention due to slowing down chemical and electrochemical corrosion simultaneously, but the poor mechanical properties cannot meet actual needs, TRIZ was used to solve the poor mechanical properties, a robust skeletal superhydrophobic perfluoropolysiloxane and polyaniline/epoxy resin composite coating was prepared, which has achieved excellent superhydrophobicity, corrosion resistance and mechanical properties.
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