介孔材料
吸附
化学
化学工程
无机化学
X射线光电子能谱
傅里叶变换红外光谱
拉曼光谱
碳纤维
材料科学
有机化学
催化作用
复合数
光学
物理
工程类
复合材料
作者
Natália Gabriele Camparotto,Gustavo Rocha Paixão,Giani de Vargas Brião,Rafael L. Oliveira,Patricia Prediger,Melissa Gurgel Adeodato Vieira
标识
DOI:10.1016/j.etap.2023.104105
摘要
In this study, mesoporous doped-carbons were synthesized from sucrose, a natural source, boric acid and cyanamide as precursors, generating B- or N-doped carbon. These materials were characterized by FTIR, XRD, TGA, Raman, SEM, TEM, BET, and XPS, confirming the preparation of a tridimensional doped porous structure. B-MPC and N-MPC showed a high surface specific area above 1000 m2/g. The effect of B and N doping on mesoporous carbon was evaluated on the adsorption of emerging pollutants from water. Diclofenac sodium and paracetamol were used in adsorption assays, reaching removal capacities of 78 and 101 mg.g-1, respectively. Kinetic and isothermal studies indicate the chemical nature of adsorption controlled by external and intraparticle diffusion and multilayer formation due to strong adsorbent/adsorbate interactions. DFT-based calculations and adsorption assays infer that the main attractive forces are hydrogen bonds and Lewis acid-base interactions.
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