水华
铜绿微囊藻
化学
藻类
环境化学
微囊藻毒素
催化作用
水处理
微囊藻
水溶液
布鲁姆
蓝藻
环境工程
环境科学
生物
生态学
浮游植物
生物化学
有机化学
细菌
营养物
遗传学
作者
Panpan Gao,Yunyi He,Shihuan Lu,Mengfan He,Zhiqun Liu,Yang Deng,Zhiquan Liu,Ting Xu,Hangjun Zhang
标识
DOI:10.1016/j.apcatb.2023.122511
摘要
The cyanobacterial blooms induced water safety problems have attracted tremendous concerns due to the adverse influences on aqueous ecosystem and human health. This study developed a novel perovskite-type catalyst for heterogeneous peroxymonosulfate (PMS) activation as an emergency measure to remove harmful algae. The results indicated that significant removal efficiency of Microcystis aeruginosa cells (97%) and chlorophyll-a (100%) was achieved within 20 min in La2CuO4/PMS system without significant release of dissolved organic carbon and metals in water. •OH, SO4•-, 1O2 and •O2- generated were all responsible for algae inactivation and subsequent algal organic matters removal. Moreover, the heterogeneous catalytic mechanism was proposed that La portion in La2CuO4 favored the cells destabilization by increasing zeta potential of algae suspension, while variable Cu portion facilitated the electron transfer to improve the yields of •OH and SO4•-. This study demonstrates that the new catalytic PMS process promises viable and effective control of harmful algal bloom impacts in water treatment.
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