异质结
光催化
降级(电信)
材料科学
量子点
盐酸四环素
铋
化学工程
光降解
光化学
纳米技术
化学
光电子学
四环素
催化作用
有机化学
电子工程
冶金
抗生素
工程类
生物化学
作者
Liang Shi,Jiangning Yin,Yanru Liu,Hanqiong Liu,Hao Zhang,Hua Tang
出处
期刊:Chemosphere
[Elsevier]
日期:2022-12-01
卷期号:309: 136607-136607
被引量:12
标识
DOI:10.1016/j.chemosphere.2022.136607
摘要
The development of highly efficient photocatalysts is vital for solvinge the problem of environmental pollution. In this study, a novel zero-/two-dimensional (0D/2D) S-scheme heterojunction was fabricated by integrating 0D copper phosphide (Cu3P) quantum dots (QDs) with a size in the range of 3-8 nm onto 2D bismuth oxychloride (BiOCl) nanosheets using a self-assembly tactic. The Cu3P/BiOCl presented intimate interface contact and high photocatalytic activity for the degradation of antibiotics (tetracycline hydrochloride (TC), oxytetracycline, ofloxacin). The optimal sample exhibited the highest photocatalytic TC degradation, with a total removal rate of 86% after 6 min under full-spectrum irradiation, which was higher than that of compared to individual BiOCl. The improved activity of the Cu3P/BiOCl heterojunction was attributed to the enhanced separation of the photogenerated carriers due to the S-scheme mode which can promote the recombination of useless photogenerated carriers and maintain photogenerated carriers with stronger redox potentials for photocatalytic reaction. In addition, employing Cu3P QDs and BiOCl nanosheets to construct an S-scheme composite can offer abundant active sites for antibiotic degradation. In brief, this study demonstrates that Cu3P QDs are an effective cocatalyst for degrading organic pollutants, which provides novel inspiration for the future design of green recycling photocatalysts for wastewater remediation.
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