化学
硅烷化
催化作用
组合化学
纳米技术
有机化学
材料科学
作者
Hwiwoong Lee,Yurim Lee,Yeonjoo Lee,Telma Kamranifard,Yunmi Lee,Byunghyuck Jung
出处
期刊:Organic Letters
[American Chemical Society]
日期:2023-12-04
卷期号:25 (49): 8932-8936
标识
DOI:10.1021/acs.orglett.3c03794
摘要
A copper-catalyzed chemo- and stereoselective method for the synthesis of (E)-2-silyl-1,3-butadienes from a broad range of allenols using mild Si-B reagents is reported in this study. Our protocol required a short reaction time at ambient temperature to produce the desired dienes in high yields. Synthetic applications are highlighted by the one-pot synthesis of tetrasubstituted arylsilanes from allenols as well as the further functionalization of C-Si bonds.
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