Highly sensitively detection of amine vapors released during shrimp spoilage by fluorescent molecules locked in covalent organic frameworks

The fluorescent sensors allow sensitive detection of amine vapors for assessing the safety and quality of seafood products. However, high diffusion resistance and insufficient recognition sites usually limit the sensitivity of the sensors. Here, we employed an emulsion-confined assembly strategy to uniform encapsulate fluorescent molecules perylene diimide (PDI) molecules into covalent organic frameworks (COFs) to achieve ultrasensitive detection of amine vapors. The detection mechanism is based on the photoinduced electron transfer from amine to the excited PDI. This method exhibits a broad linear detection range from 8 ppb to 800 ppm and the limit of detection reaches as low as 1.2 ppb. The real-time detection of the amine vapors produced during shrimp spoilage is successfully achieved with excellent performance. This provides a versatile method for the on-demand synthesis of functional materials with high fluorescence properties for the development of chemical sensors via encapsulating different fluorescent molecules into COFs.