Effect of Ce-Doping on Microstructure and Adsorption- Photodegradation Behaviors of the Hydrothermally-Synthesized TiO2 Nanotubes

Ce-doped TiO2 nanotubes (Ce-TNTs) were synthesized by a hydrothermal method to obtain high-efficiency adsorption and photodegradation abilities for methylene blue (MB) dye. The transmission electron microscope (TEM), X-ray diffractimeter (XRD), nitrogen adsorption, X-ray photoelectron spectrum (XPS), and photodegradation tests were used to characterize the morphology, microstructure, ionic valance, and degradation behaviors of the TNTs. Results show that the Ce-doped TNTs are composed of anatase tubulars with an inner-hole diameter of 5 nm, outer diameter of 10–15 nm, length of several hundred nanometers, and a small amount of CeO2 nanoparticles. Ce3+ and Ce4+are dissolved in the anatase crystals, the ratio of which increases with an increase in Ce addition. Ce-doping yields a higher amount of surface oxygen, which results in a strong physical and chemical adsorption to the cationoid MB. 2.5 mol% Ce-doping produces the largest specific surface area, porosity, and photoabsorption threshold and the lowest Zeta potential, yielding the highest adsorption efficiency and photocatalytic ability even under sunlight irradiation.