沸石咪唑盐骨架
扫描电子显微镜
材料科学
吸附
纤维素
滤纸
多孔性
分析化学(期刊)
化学工程
色谱法
化学
复合材料
金属有机骨架
有机化学
工程类
作者
Angaraj Singh,Aman Preet Singh,Ajitanshu Vedrtnam,Magdalena Wdowin
标识
DOI:10.21203/rs.3.rs-3221089/v1
摘要
Abstract ZIF-8 (zeolitic imidazolate framework-8) has emerged as a highly promising material for CO 2 capture due to its outstanding adsorption capacity and selectivity. In the present study, ZIF-8 and a ZIF-8-based cellulose air filter (ZCAF) were synthesized using a rapid synthesis route and the kraft pulping method, respectively. The synthesized ZIF-8 and ZCAF samples were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The SEM analysis revealed a rhombic dodecahedron morphology characterized by rough and porous features, while energy-dispersive X-ray (EDX) analysis confirmed the presence of constituent elements. Furthermore, XRD analyses demonstrated that all observed peaks and bands aligned with the crystalline structure present in the prepared samples. The particle size of the synthesized ZIF-8 samples varied based on the synthesis parameters, measuring approximately 99.46 nm, 101.9 nm, and 105.7 nm. To develop a ZIF-8-based air filter for CO 2 capture, the ZIF-8 crystals were incorporated into a filter medium. The resulting ZIF-8-based air filter demonstrated significant improvements in CO 2 loading compared to the standard MEA (monoethanolamine) reference. The calculated percentage increase in CO 2 loading was approximately 41% for ZIF-8 (ZS3) and 22% for ZCAF (ZCAF3) samples respectively, relative to the MEA reference.
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