烯烃
催化作用
镍
对偶(语法数字)
化学
组合化学
光化学
光催化
有机化学
光催化
哲学
语言学
作者
Anilkumar Kommoju,Kattamuri Snehita,K. Sowjanya,Saratchandra Babu Mukkamala,Kishor Padala
摘要
Alkene carbofunctionalization reactions have great potential for synthesizing complex molecules and constructing complex structures in natural products and medicinal chemistry. Recently, dual photoredox/nickel catalysis has emerged as a novel strategy for alkene carbofunctionalization. Nickel offers numerous advantages over other transition metals, such as cost-effectiveness, abundance, and low toxicity, and moreover, it has many oxidation states. Nickel catalysts exhibit excellent catalytic activity in dual photoredox/transition metal catalysis, facilitating the formation of carbon-carbon or carbon-heteroatom bonds in organic transformations. This review highlights the latest advancements in dual photoredox/nickel-catalyzed alkene carbofunctionalizations and includes the literature published from 2020 to 2024.
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