Study of Copper Separation from Ternary Black Powder Leaching Solution Using P204 (D2EHPA) Multistage-Extraction

Nickel and cobalt recovered from ternary leaching solutions have high market value and stability. In addition to preventing environmental damage, this recovery process is also very useful in the application of power energy storage and electric vehicles. Solvent extraction is an effective and selective method for separating elements in ternary leaching solutions. This research focuses on the separation stage of feed solution impurities, especially Cu, by optimizing the extraction process using multi-stage extraction. This method, which is adapted to a laboratory scale, mixes the feed solution with saponified P204 (prepared with NaOH) and then stirred until phase separation into a loaded organic phase and raffinate occurs. The use of P204 with 3-stage extractions with O/A= 1.5/1 and pH= 4.5 succeeded in separating 99.96% extraction of Cu with a primary yield of Cu value of 99.999%. This solvent extraction also successfully separated 99.23% of Mn, Ca=95.62%, and other impurity metals such as Fe, Zn, Li, and Si reaching a final concentration in the raffinate solution of only 10 -3 g/L. The results of this research are very useful in the subsequent extraction process in the form of separating the valuable elements nickel and cobalt. This method can potentially overcome environmental problems resulting from the disposal of NCM battery waste in the metallurgical field.