光催化
材料科学
可见光谱
光电流
水溶液
吸收(声学)
兴奋剂
光化学
纳米技术
化学工程
催化作用
化学
光电子学
物理化学
有机化学
复合材料
工程类
作者
Bo Liu,Wei Hu,Jayanta Kr. Nath,Jing Tong,Xudong Hou,Wenlong Liu,Jinlong Yang
出处
期刊:Dalton Transactions
[The Royal Society of Chemistry]
日期:2017-01-01
卷期号:46 (3): 678-684
被引量:31
摘要
We present a novel strategy to improve the stability and optical absorption of polyoxotitanates (POTs) via concurrently fully carboxylate-coordinating and hetero-metal-doping, and illustrate the strategy by an indium doped hetero-polyoxotitanate (h-POT) of a [Ti12In6O18(OOCC6H5)30] (POTi12In6) nanocluster, which possesses ultrahigh stability in both acid and base aqueous solutions. The nanocluster structurally features a core-shell double wheel structure and a polar cavity. Both experiments and theoretical calculations confirm the semiconductive properties of the nanocluster. Under visible irradiation the POTi12In6 nanocluster can produce pronounced photocurrent, and reactive oxygen species for pollutant degradation. Without using any cocatalyst, POTi12In6 exhibits important visible-light-driven photocatalytic activity for H2 evolution in an aqueous system. This work could render a polyoxotitanate as a new type of visible-photoactive photocatalyst.
科研通智能强力驱动
Strongly Powered by AbleSci AI