Ultrathin and Highly Tough Hydrogel Films for Multifunctional Strain Sensors

With good flexibility and biocompatibility, hydrogel-based sensors have been widely used in human motion detection, artificial intelligence, human–machine interface, and other fields. Previous research on hydrogel-based sensors has focused on improving the mechanical properties and signal transmission sensitivity. With the development of human smart devices, there is an increasing demand for hydrogel sensor comfort and more application functions, such as ultrathin structures and recognition functions for contact surfaces, which are realized with higher requirements for the thickness, flexibility, friction resistance, and biocompatibility of hydrogels. Inspired by the ultrathin and flexible characteristics of human organ biofilms, we constructed conductive hydrogel films by using the flim-casting and glycerol–H2O secondary hydration methods. This ultrathin structure enables the hydrogel films to have a high elongation at break of 523.3%, a stress of 3.5 MPa, and a good friction resistance. Combined with the excellent sensing properties (gauge factor = 2.1 and a response time of 200 ms), the hydrogel film-based sensor can not only record human motion signals but also recognize the surface texture and roughness of objects, such as glass, brushes, wood, and sandpaper with mesh sizes of 80, 50, and 24, accurately. In addition, this hydrogel film has a series of excellent properties such as UV shielding, antiswelling ability, and good biocompatibility. This research provides a novel way for the development of emerging soft-material smart devices, such as hydrogel-based electronic skin and soft robots.