化学
金属有机骨架
热重分析
间苯二甲酸
结晶度
醋酸
表面改性
物理吸附
水溶液中的金属离子
荧光
水溶液
热稳定性
检出限
粉末衍射
无机化学
金属
有机化学
物理化学
吸附
结晶学
色谱法
物理
聚酯纤维
量子力学
对苯二甲酸
作者
Subhrajyoti Ghosh,Felix Steinke,Abhijeet Rana,Masud Alam,Shyam Biswas
标识
DOI:10.1002/ejic.202100568
摘要
Abstract A new MOF named Al‐CAU‐10‐OC 3 H 5 is presented (MOF=metal‐organic framework, CAU=Christian‐Albrechts‐University). The material ( 1 ) was prepared by incorporating an allyloxy functionalized 5‐(allyloxy)isophthalic acid (H 2 AIA) as a linker via a traditional solvothermal procedure. Various analytical tools such as FT‐IR, PXRD, thermogravimetric and N 2 physisorption analyses were utilized to characterize the material. Material 1 is stable up to 350 °C in argon environment. It also showed good stability of its framework in acetic acid, 1 (M) HCl, water, methanol, ethanol and acetone. The activated form of material 1 (named 1′ ) displayed sensitive recognition of Pd(II) ion having great specificity in water through “turn‐off” fluorescence signal. When the potentially competitive analytes were present, the probe can also recognize Pd 2+ ion selectively. The values of Stern‐Volmer constant (1.05×10 5 M −1 ) and detection limit (26.24 ppb) prove the remarkable sensing ability of this probe. Furthermore, from the PXRD study after Pd 2+ sensing, it was observed that the peak position and crystallinity of the MOF were very similar with the activated MOF which suggest the maintenance of structural integrity during the sensing experiment. Hence, the probe is highly effective for the sensing of Pd 2+ . In addition, the sensing mechanism has been investigated comprehensively.
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