共聚物
高分子化学
单体
化学
氮丙啶
羟甲基
电泳剂
亚乙基亚胺
亲核细胞
侧链
有机化学
聚合物
催化作用
戒指(化学)
作者
S. Amalia Pooley,Guido S. Canessa,Bernabé L. Rivas
标识
DOI:10.1002/(sici)1521-3935(19981001)199:10<2293::aid-macp2293>3.0.co;2-7
摘要
The copolymerization of 1,2,3,6-tetrahydrophthalic anhydride (THPhA) as electrophilic monomer and N-(2-hydroxyethyl)ethyleneimine1 Systematic name: N-(2-hydroxyethyl)aziridine. as nucleophilic monomer in acetonitrile without initiator was investigated. The copolymers show low incorporation of THPhA in the main chain and preferential incorporation in the side chain by esterification reaction of the hydroxymethyl group. On the basis of the spectroscopic data a copolymer structure is proposed.
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