荧光粉
发光
兴奋剂
分析化学(期刊)
材料科学
结构精修
杂质
扫描电子显微镜
晶体结构
磷灰石
光电子学
离子
橙色(颜色)
相(物质)
粉末衍射
矿物学
化学
结晶学
有机化学
色谱法
复合材料
食品科学
作者
Haikun Liu,Kun Nie,Yuanyuan Zhang,Lefu Mei,Dina V. Deyneko,Xiaoqian Ma
标识
DOI:10.1016/j.jre.2022.06.007
摘要
A series of single-phase and color-tunable phosphors Sr2La3(SiO4)3F:0.15Tb3+,xSm3+ (SLSOF:0.15Tb3+,xSm3+) was prepared using solid-state route. The X-ray diffraction (XRD) was used to characterize the phase of the as-prepared samples. The synthesized phosphors have apatite-type structure without other impurities. Sm3+ and Tb3+ ions substitute La3+ into the lattice and form a single-phase solid solution. The elements are evenly distributed in the sample according to the scanning electron microscopy (SEM) results. The crystal structure of the host phosphor was refined by the Rietveld method. The optical properties were studied in detail by investigation of the luminescence and diffuse spectra, fluorescence decay curves and energy transfer efficiency. The phosphor color can be changed from green (0.29, 0.48) to yellow/orange and red (0.57, 0.42) via adjusting the doping ratio of Sm3+. The SLSOF:0.15Tb3+,xSm3+ phosphors can emit typical multicolor light such as green, yellow, orange and red with gradually increasing Sm3+ doping concentration. All results indicate the occurrence of the energy transfer which results in the color-tunable properties of the phosphors.
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