发光
化学
猝灭(荧光)
激活剂(遗传学)
电子转移
荧光粉
原子物理学
光化学
化学物理
光电子学
荧光
材料科学
物理
光学
生物化学
基因
作者
Qincan Ma,Qiang Zhang,Yang Mei,Baiqi Shao,Ruizhuo Ouyang,Ning Guo
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2022-06-14
卷期号:61 (25): 9823-9831
被引量:14
标识
DOI:10.1021/acs.inorgchem.2c01386
摘要
Bi3+-related metal-to-metal charge transfer (MMCT) transition phosphors are expected to become a new class of solid-state luminescent materials due to their unique broadband long-wavelength emission; however, the main obstacle to their application is the thermal quenching effect. In this study, one novel thermal quenching mechanism of Bi3+-MMCT transition luminescence is proposed by introducing electron-transfer potential energy (ΔET). Y0.99V1-xPxO4:0.01Bi3+ (YV1-xPxO4:Bi3+) is used as the model; when the band gap of the activator Bi3+ increases from 3.44 to 3.76 eV and the band gap of the host YV1-xPxO4 widens from 2.75 to 3.16 eV, the electron-transfer potential energy (ΔET) decreases and the thermal quenching activation energy (ΔE) increases, which result in the relative emission intensity increasing from 0.06 to 0.64 at 303-523 K. Guided by density functional calculations, the thermal quenching mechanism of the Bi3+-MMCT state transition luminescence is revealed by the double-band-gap modulation model of the activator ion and the matrix. This study improves the thermal quenching theory of different types of Bi3+ transition luminescence and offers one neo-theory guidance for the contriving and researching of high-quality luminescence materials.
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