Novel Alkane Dehydrogenation Routes via Tailored Catalysts

Abstract Alkane dehydrogenation to alkene represents a promising alternative route for conventional petroleum cracking processes heavily reliant on fossil resources. This Concept outlines the latest advancements of novel alkane dehydrogenation routes that offer potential solutions to intrinsic problems existing in routine direct dehydrogenation or oxidative dehydrogenation reactions, including CO 2 assisted alkane dehydrogenation, chemical looping alkane oxidative dehydrogenation, dual‐path dehydrogenation and auto‐accelerated multiple alkane dehydrogenation route. These novel reaction routes exhibit unique advantages in enhancing the activity, selectivity and stability of the alkane dehydrogenation reaction system. The rational design of novel catalysts and proper choice of the reaction condition that well‐fitted these reaction routes is the key for achieving highly efficient and stable alkane dehydrogenation process. These present examples in this manuscript also highlight the importance of fundamental in‐depth understandings on the mechanism and structure‐function relations, which is the foundation for developing novel alkane dehydrogenation routes for practical applications.