A Bifunctional Coordination‐Chain‐Based Hydrogen‐Bonded Framework for Quantitative Enantioselective Sensing

Enantioselective sensing is highly crucial and challenging due to the highly similar physical/chemical properties of enantiomers which may have different chemical impact on organism. Luminescent coordination compounds have attracted great attention as sensing materials based on their controllable chemical and electric structures that can be highly matched with the targeted species. To achieve high-performance enantioselective sensing, the direct synthesis of chiral and luminescent bifunctional coordination compounds is a rational way but highly challenging due to the price and synthesis difficulty. Herein, an anionic coordination-chain-based hydrogen-bonded framework was applied as a host to accommodate chiral and luminescent centers via a facile cation exchange reaction, affording a bifunctional framework that possesses enantioselective sensing properties for the mixture of enantiomers. This study paves a pathway for constructing multifunctional coordination chain-based hydrogen-bonded frameworks for rapidly enantioselective sensing function.