Iron Nanoparticle-Incorporated Laser-Induced Graphene Filters for Environmental Remediation via an In Situ Electro-Fenton Process

Laser-induced graphene (LIG) has garnered much attention due to its facile and chemically free fabrication technique. Metal nanoparticle incorporation into the LIG matrix can improve its electrical and catalytical properties for environmental application. Here, we demonstrate the fabrication of nanoscale zerovalent iron (nZVI) nanoparticle-incorporated LIG (Fe-LIG) and sulfidized-nanoscale zerovalent iron (S-nZVI) nanoparticle-incorporated LIG (SFe-LIG) surfaces. The sheets were first fabricated to investigate nanoparticle loading, successful incorporation in the LIG matrix, and electrochemical performance as electrodes. Fe-LIG and SFe-LIG sheets showed ∼3-3.5 times more charge density as compared with the control LIG sheet. The XPS and its deconvolution confirmed the presence of nZVI and S-nZVI in the Fe-LIG and SFe-LIG surfaces, which can generate