化学
吡唑啉
分子内力
离域电子
荧光
光化学
水溶液中的金属离子
选择性
离子
显色的
螯合作用
金属
组合化学
无机化学
立体化学
有机化学
物理
色谱法
量子力学
催化作用
作者
Md. Mohasin,Md. Zafer Alam,Alimuddin Alimuddin,Qasim Ullah,Mohammed Arifuddin,Salman A. Khan
标识
DOI:10.1080/00958972.2023.2299963
摘要
Pyrazoline derivatives exhibit potential application as sensitive and selective chemosensors for the recognition of Fe3+ ions. Their distinctive structure has both donating and accepting sites and is delineated by delocalized orbitals. Through intramolecular charge transfer (ICT), ligand-to-metal charge transfer (LMCT), chelation-enhanced quenching (CHEQ), and H-bond interactions, pyrazoline derivatives show remarkable chromogenic and fluorogenic capabilities. The pyrazoline sensors demonstrated excellent selectivity, low detection limit, and precise metal ion detection. This mini-review provides a guide for utilizing pyrazoline-based "On–Off" chemosensors to identify Fe3+ in diverse fields.
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