Charge Dynamics and Defect States under “Spot‐Light”: Spectroscopic Insights into Halide Perovskite Solar Cells

Halide perovskite solar cells (PSCs) have shown remarkable power conversion efficiencies. However, the inherent defect issues of perovskite materials still limit their performance and long‐term stability, resulting in lifespans far from commercial standards. With their noninvasive approach to probing the electronic and vibrational properties of materials, spectroscopic techniques have become crucial tools for uncovering and understanding defect states and complex charge carrier dynamics in halide perovskites. This review explores the application of various advanced spectroscopic techniques in PSCs to elucidate the complex behaviors of charge carriers within PSCs. These techniques reveal detailed temporal and spatial distributions of charge carriers, enabling precise analysis of defect impacts and interfacial charge transfer processes. By integrating spectroscopic data, it is possible to more accurately identify and mitigate defect‐induced nonradiative recombination and charge transfer, thereby enhancing the stability and efficiency of PSCs. This comprehensive spectroscopic understanding is crucial for developing innovative technologies to accelerate the commercial viability of PSCs.