Facile Synthesis of Sn/Nitrogen-Doped Reduced Graphene Oxide Nanocomposites with Superb Lithium Storage Properties

Sn/Nitrogen-doped reduced graphene oxide (Sn@N-G) composites have been successfully synthesized via a facile method for lithium-ion batteries. Compared with the Sn or Sn/graphene anodes, the Sn@N-G anode exhibits a superb rate capability of 535 mAh g−1 at 2C and cycling stability up to 300 cycles at 0.5C. The improved lithium-storage performance of Sn@N-G anode could be ascribed to the effective graphene wrapping, which accommodates the large volume change of Sn during the charge–discharge process, while the nitrogen doping increases the electronic conductivity of graphene, as well as provides a large number of active sites as reservoirs for Li+ storage.