光致变色
二芳基乙烯
光化学
发色团
构象异构
氧化还原
二茂铁
荧光
分子开关
材料科学
位阻效应
反平行(数学)
化学
分子
立体化学
有机化学
电化学
光学
电极
物理化学
量子力学
磁场
物理
冶金
作者
Yunsong Cai,Ya Gao,Qianfu Luo,Mengqi Li,Junji Zhang,He Tian,Weihong Zhu
标识
DOI:10.1002/adom.201670048
摘要
On page 1410, a new gated photochromism and fluorescence switches are successfully achieved in a ferrocene-modified diarylethene system with a sterically hindered ethene bridge. The photoinactive parallel conformer and photoactive antiparallel conformer are individually investigated by W.-H. Zhu and co-workers. The different conformers show redox-gated photochromism and reversible redox reactions can also switch the fluorescence of the naphthalimide chromophore “ON” and “OFF”.
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