Application and Prospects of EMOFs in the Fields of Explosives and Propellants

推进剂 爆炸物 航空航天工程 材料科学 核工程 环境科学 化学 工程类 有机化学
作者
Bojun Tan,Jinkang Dou,Xiong Yang,Wenjie Li,Jing Zhang,Pengfeng Zhang,Hongchang Mo,Xinming Lu,Bozhou Wang,Ning Liu
出处
期刊:Dalton Transactions [Royal Society of Chemistry]
卷期号:53 (32): 13308-13319 被引量:2
标识
DOI:10.1039/d4dt01537a
摘要

Energetic Metal-Organic Framework (EMOF) compounds have gained significant attention in recent years as a hot research topic in the fields of explosives and propellants. This article provides an overview of the latest research progress of EMOFs in various areas, including heat-resistant explosives, burning rate catalysts and initiating explosives. It discusses the recent development trends of high-energy EMOFs, such as high-dimensional and solvent-free structural design, simplified and scalable synthesis conditions, environmentally friendly manufacturing processes with tunable structures, high-energy, low-sensitivity and multifunctional target products. The challenges and issues faced by EMOFs in heat-resistant explosives, burning rate catalysts and initiating explosives are presented. Furthermore, the key research directions for future applications of EMOFs in the fields of explosives and propellants are discussed, including solvent-free high-dimensional EMOFs design and synthesis, precise modulation of EMOFs molecular composition and pore structure, improvement of accurate prediction methods for physicochemical properties of high-energy EMOFs, low-cost large-scale production and development of multifunctional composite EMOFs as energetic materials, exploration of influencing factors, and comprehensive study on the application of novel and high-performance multifunctional EMOFs.
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