Oxygen Vacancy Activates the Second-Nearest-Neighbor Lattice Oxygen for Oxidation Reaction

Oxygen vacancies on the oxide surface are regarded to play critical roles in catalytic oxidation reactions because they can alter the electronic and geometric properties of oxide catalysts. However, the effects of the oxygen vacancy on the CO oxidation activity of the surrounding lattice oxygen have remained elusive. In this work, using high-pressure scanning tunneling microscopy we identify that oxygen vacancy can activate surface lattice oxygen on the Mn