费托法
催化作用
钴
锆
高分辨率透射电子显微镜
材料科学
氧化钴
金属
选择性
氧化物
过渡金属
离解(化学)
X射线光电子能谱
吸附
合成气
无机化学
化学工程
化学
纳米技术
物理化学
透射电子显微镜
冶金
有机化学
工程类
作者
Congbiao Chen,Yan Liu,Qiang Wang,Bo Hou,Jungang Wang,Shupeng Guo,Litao Jia,Debao Li
出处
期刊:Fuel
[Elsevier]
日期:2024-03-01
卷期号:359: 130405-130405
标识
DOI:10.1016/j.fuel.2023.130405
摘要
It is reported that Zirconium (Zr) is an effective promoter of cobalt-based catalysts for Fisher-Tropsch synthesis (FTS). Numerous studies have been conducted to explore the nature of the promotion. However, many of these studies focus on oxide-supported cobalt-based catalysts, in which the support effects may have partially enhanced or masked the influences of Zr. In the present work, CoZr catalysts without oxide support have been prepared across a wide range of Zr/Co molar ratio from 0.04 to 0.33 to investigate the nature of the Zr promotion. Comparing with the nano-Co3O4, the promoted catalysts exhibit excellent performance. The reaction temperature required to convert the same amount of syngas on the same amount of cobalt has decreased by about 40 °C. The selectivity of C5+ has increased from 70∼81% to over 85% at the same CO conversion, and even higher than 90% on the CoZr catalysts with high Zr/Co ratio. Evidences from multiple techniques, including in situ XPS, CO-DRIFTs, CO-TPD, NH3-TPD, Py-IR, HRTEM, Raman and XRD, shows that Zr tends to occupy the coordinately unsaturated sites of nano-Co3O4. After reduction, Zr enters the lattice of Co metal, leading to the lattice expansion. Benefitting from the Zr induced structural changes of the Co metal, CO adsorption and dissociation on the CoZr catalysts have been enhanced. Besides, due to the strong interaction between Co and Zr, the growth of the Co metal crystal during H2 reduction and O atoms adsorption on the reduced catalysts surface are inhibited significantly, which make more Co atoms available during FTS reaction. As a result, the catalytic performances are improved obviously.
科研通智能强力驱动
Strongly Powered by AbleSci AI