电解质
电化学
制作
钾
氧化物
阴极
材料科学
电极
纳米技术
过渡金属
储能
离子
化学工程
化学
催化作用
冶金
有机化学
物理化学
病理
功率(物理)
工程类
物理
替代医学
医学
量子力学
作者
Zhuangzhuang Zhang,Qiao Hu,Jiaying Liao,Yifan Xu,Liping Duan,Ruiqi Tian,Yichen Du,Jian Shen,Xiaosi Zhou
出处
期刊:Nano Letters
[American Chemical Society]
日期:2023-01-11
卷期号:23 (2): 694-700
被引量:27
标识
DOI:10.1021/acs.nanolett.2c04649
摘要
Layered transition-metal (TM) oxides have drawn ever-growing interest as positive electrode materials in potassium-ion batteries (PIBs). Nevertheless, the practical implementation of these positive electrode materials is seriously hampered by their inferior cyclic property and rate performance. Reported here is a self-templating strategy to prepare homogeneous P2-K0.6CoO2 (KCO) microcubes. Benefiting from the unusual microcube architecture, the interface between the electrolyte and the active material is considerably diminished. As a result, the KCO microcubes manifest boosted electrochemical properties for potassium storage including large reversible capacity (87.2 mAh g-1 under 20 mA g-1), superior rate performance, and ultralong cyclic steady (an improved capacity retention of 86.9% under 40 mA g-1 after 1000 cycles). More importantly, the fabrication approach can be effectively extended to prepare other layered TM oxide (P3-K0.5MnO2, P3-K0.5Mn0.8Fe0.2O2, P2-K0.6Co0.67Mn0.33O2, and P2-K0.6Co0.66Mn0.17Ni0.17O2) microcubes and nonlayered TM oxide (KFeO2) microcubes.
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