Atropisomerization of Biaryl Cr(CO)3 Complexes: Preparation of Both Atropisomers of Biaryls

All articles of this category Both enantiomerically pure biaryls with an axial chirality can be prepared from a single planarly chiral (arene)Cr(CO) 3 complex by Suzuki-Miyaura cross-coupling and subsequent axial isomerization. chiral biaryl - axial chirality - planar chirality - axial isomerization - (arene)chromium complex