ChemInform Abstract: A Model for the Prediction of Electron‐Transfer Rates in the Highly Exergonic Region, Applied to the Reaction Between Solvated Electrons and Arenes in Tetrahydrofuran.

Abstract Anharmonic oscillator perturbations to the classical model of outer‐sphere electron‐transfer reactions are examined and used to fit rate constant data (from literature for molecules such as given in the scheme) in the exergonic Marcus‐invented region.