羟醛反应
乙醇醛
醛缩酶A
化学
甘油醛
醛
醛缩酶B
果糖
果糖二磷酸醛缩酶
酶
催化作用
有机化学
立体化学
脱氢酶
作者
Xavier Garrabou,José A. Castillo,Christine Guérard‐Hélaine,Teodor Parella,Jesús Joglar,Marielle Lemaire,Pere Clapés
标识
DOI：10.1002/anie.200902065
摘要
New facets of enzyme activity: D-Fructose-6-phosphate aldolase (FSA) catalyzes the self-aldol reaction of glycolaldehyde (GA) and its cross-aldol addition to other aldehydes. As the affinity of GA for FSA as a donor is higher than that as an acceptor, cross-aldol reactions are possible with good to poor aldehyde acceptors if the concentration of GA in the reaction is kept low.
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