Improved DC flashover performance of epoxy insulators in SF6 gas by direct fluorination

In order to prove the effectiveness of direct fluorination in improving dc flashover performance of epoxy insulators in SF ₆ gas and also to provide evidence for the importance of surface conductivity of solid insulators, sheet-shaped and truncated cone epoxy samples were prepared and were fluorinated in a laboratory stainless vessel using a F ₂ /N ₂ mixture with 12.5% F ₂ by volume at 0.1 MPa and 85 °C for 30 min. Physicochemical characteristics of the fluorinated surface layer were evaluated by ATR-FTIR and SEM techniques, and the results showed substantial chemical modification of the surface layer, which has a thickness of 0.89 μm and a roughened surface. Further, as expected on the basis of previous studies, measurements of surface electrical properties of the surface fluorinated sample, compared to the unfluorinated one, revealed a four orders of magnitude higher surface conductivity and a much more rapid decay of surface potential after corona charging. Dc flashover tests were performed on the truncated cone samples in SF ₆ gas at 0.1 MPa with a stepwise increasing voltage before and after the fluorination. The flashover test results showed a definite improvement in dc flashover voltage. For example, the flashover voltage at 63.2% probability or the mean flashover voltage for 2 min duration of the voltage step increased by 13.8% or 13.6% after the fluorination. The performance improvement is mainly attributed to easy leakage and dispersion of the charge deposited on the surface fluorinated sample from the gas phase, due to high conductivity of the fluorinated layer. The flashover test results also showed the influences of the duration of the voltage step on the flashover voltage and on the increase rate of flashover voltage. This means that even the time constant of the fast gas phase charging should be larger than 2 min, and that there should be different influences of the inhomogeneous surface conduction between the virgin sample and the fluorinated sample.