塔菲尔方程
分解水
析氧
材料科学
过电位
电解质
镍
腐蚀
电极
化学工程
阳极
海水
无机化学
电化学
催化作用
冶金
化学
生物化学
海洋学
物理化学
光催化
工程类
地质学
作者
Wei-Hsuan Hung,Bing Xue,Tung Ming Lin,Sheng-Yuan Lu,I-Yu Tsao
标识
DOI:10.1016/j.mtener.2020.100575
摘要
The oxygen evolution reaction (OER) is the half reaction in the overall reaction of electrocatalytic water splitting, and it involves four electron transfers. The aforementioned electron requirement implies that the OER requires more energy than the HER, thus limiting the overall water splitting efficiency. Here, we propose a novel anode catalyst by using an advanced composite material of selenized nickel–iron electrodes together with NiFe_LDH. An analysis of the water splitting performance was carried out in different concentrations of a seawater-like electrolyte, which, in terms of corrosion reactions, is a relatively harsher environment than that found in natural seawater. In this study, we discovered that a Se_NiFe foam electrode with an LDH layer exhibited extraordinary stability and activity in an aqueous sea-like solution, demonstrating an improved overpotential from the original 1.62 V–1.43 V in a seawater electrolyte mixture. Furthermore, the Tafel slope significantly decreased from 115.1 mV dec−1 to 26.3 mV dec−1. Notably, the lifespan of this novel electrode was extended from 80 h to 250 h. The mechanism of improved stability and corrosion resistance is also investigated in this study.
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