Photochromic Metal–Organic Framework for High-Resolution Inkless and Erasable Printing

Inkless and erasable printing as a new technology has received intense attention in reducing paper waste and environmental hazards caused by the use of large amounts of ink. However, achieving high-resolution printing by inkless and erasable printing for practical applications remains a huge challenge. Herein, a new metal-organic framework (MOF) has been synthesized, which exhibits a reversible photochromic behavior. None of the unpaired electrons of metal ions and a unique three-dimensional network hinder electron transfer between the ligands and metal nodes, as well as between the ligands themselves, which are conducive to prolonging the photo-generated color lifetime and suitable for inkless and erasable printing. By virtue of the proper photo-generated color lifetime, strong contrast color before and after light irradiation, and reversible color transformation, a high-resolution printing content for inkless and erasable printing can be achieved by light irradiation. Notably, the paper coated with this MOF can be used for printing not only simple patterns such as pictures but also even texts for practical applications, surpassing other photochromic MOF materials for inkless and erasable printing, and almost comparable to ink and laser printing in terms of practicality and resolution. In addition, the MOF-coated paper can be reused for multiple cycles without significant deterioration.