纳米花
材料科学
阳极
纳米片
纳米技术
碳化
化学工程
退火(玻璃)
电极
纳米结构
复合材料
扫描电子显微镜
化学
物理化学
工程类
作者
Nabilah Al‐Ansi,Abdulwahab Salah,Q.A. Drmosh,Guo-Duo Yang,Abdo Hezam,Adel Al-Salihy,Jian Lin,Xiaohong Wu,Liang Zhao,Jingping Zhang,Shaolei Wang,Hai‐Zhu Sun
出处
期刊:Small
[Wiley]
日期:2023-08-30
卷期号:19 (52)
被引量:5
标识
DOI:10.1002/smll.202304459
摘要
Despite being one of the most promising materials in anode materials, molybdenum sulfide (MoS2 ) encounters certain obstacles, such as inadequate cycle stability, low conductivity, and unsatisfactory charge-discharge (CD) rate performance. In this study, a novel approach is employed to address the drawbacks of MoS2 . Carbon polymer dots (CPDs) are incorporated to prepare three-dimensional (3D) nanoflower-like spheres of MoS2 @CPDs through the self-assembly of MoS2 2D nanosheets, followed by annealing at 700 °C. The CPDs play a main role in the creation of the nanoflower-like spheres and also mitigate the MoS2 nanosheet limitations. The nanoflower-like spheres minimize volume changes during cycling and improve the rate performance, leading to exceptional rate performance and cycling stability in both Lithium-ion and Sodium-ion batteries (LIBs and SIBs). The optimized MoS2 @CPDs-2 electrode achieves a superb capacity of 583.4 mA h g-1 at high current density (5 A g-1 ) after 1000 cycles in LIBs, and the capacity remaining of 302.8 mA h g-1 after 500 cycles at 5 A g-1 in SIBs. Additionally, the full cell of LIBs/SIBs exhibits high capacity and good cycling stability, demonstrating its potential for practical application in fast-charging and high-energy storage.
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