光催化
材料科学
纳米棒
X射线光电子能谱
可见光谱
纳米复合材料
兴奋剂
化学工程
降级(电信)
异质结
纳米颗粒
纳米技术
光电子学
催化作用
化学
电信
生物化学
计算机科学
工程类
作者
Ali Abrishami-Rad,Abbas Sadeghzadeh‐Attar
标识
DOI:10.1016/j.jtice.2023.105110
摘要
Designing and constructing heterogeneous structures is an effective approach employed to improve photocatalytic performance. This study aimed to use Fe-doped BiVO4/SnO2 nanocomposites for photocatalytic degradation of Basic Red 46 (BR46) dye under visible-light irradiation. BiVO4 nanoparticles doped with varying amounts of Fe were synthesized using the sol-gel method and interspersed on SnO2 nanorods with an average diameter of about 100 nm fabricated using the liquid phase deposition (LPD) process. FE-SEM, EDX, XRD, FT-IR, XPS, BET, DRS, and PL analysis were used to characterize the morphology and structure of the samples. The 1.5 wt% Fe-doped BiVO4/SnO2 nanocomposite exhibited the highest visible-light photoactivity with excellent stability, resulting in complete degradation of BR46 within 90 min of irradiation. The boost photocatalytic activity of Fe-doped BiVO4/SnO2 nanocomposite can be attributed to the enhanced separation of photo-generated carriers derived from synergistic effects by the BiVO4/SnO2 heterostructure, Fe doping in BiVO4 lattice, and partly the extended light absorption ability. These findings show that designing a heterogeneous BiVO4/SnO2 structure with Fe-doping can be a promising strategy for the application in constructing efficient and stable photocatalysts for the degradation of dyes from industrial wastewater pollutions.
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