芳基
化学
电泳剂
镍
催化作用
镁
氯化物
劈理(地质)
键裂
氯化锂
锂(药物)
有机化学
药物化学
组合化学
烷基
医学
岩土工程
断裂(地质)
工程类
内分泌学
作者
Jing‐Ao Ren,Cong Xue,Chao Gui,Changwen Miao,Xue‐Qiang Chu,Hao Xu,Xinxing Zhou,Mengtao Ma,Zhi‐Liang Shen
标识
DOI:10.1002/adsc.202300663
摘要
Abstract A step‐economical and operationally simple nickel‐catalyzed cross‐electrophile coupling of aryl phosphates with aryl bromides through C−O bond cleavage, which precluded the employment of relatively moisture‐labile and unreadily available organometallics, was developed. The reaction proceeded smoothly in the presence of magnesium turnings and lithium chloride in THF to afford the corresponding biaryls in moderate to good yields with reasonable functionality tolerance.
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