激进的
光化学
发光
材料科学
水溶液
分子间力
分子
氨
羟基自由基
组合化学
有机化学
化学
光电子学
作者
Juanjuan Liu,Huajie Yu,Farhan Siddique,Gleb V. Baryshnikov,Hongwei Wu
标识
DOI:10.1021/acsami.3c14730
摘要
Developing a free radical emission system in different states, especially in water, is highly challenging and desired. Herein, a host–guest coassembly strategy was used to protect the in situ photoactivated radical emission of carbonyl compounds in solid and aqueous solutions by doping them into a series of small molecules with hydroxyl groups. The intermolecular interactions between host and guest and the electron-donating ability of the hydroxyl group can significantly promote the formation and stabilization of luminescence by carbonyl radicals. Accordingly, the stimuli-responsive property of the free radical system was investigated in detail, and the self-assembled aggregates showed photoactive and thermoresponsive behaviors. In addition, an advanced ammonia compound identification system can be built based on a radical emission system. Our design strategy sheds light on developing free radical systems that can emit in various states, which will greatly broaden the application range of free radicals.
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