The Chemistry of α‐Enolizable Alkynones: A Comprehensive Review

Abstract This comprehensive review summarizes the published literature data concerning the chemistry of α‐enolizable alkynones, also denoted aliphatic or C−H active alkynones, where an alkyl group is adjacent to the carbonyl function, from the first example in 1949 to the present day. Starting from a historical perspective, the reader will be introduced to the recent achievements and future challenges in this field. The review covers around 100 references.