对苯二酚
介电谱
分析化学(期刊)
循环伏安法
材料科学
电极
扫描电子显微镜
儿茶酚
检出限
光谱学
水平扫描速率
核化学
化学
电化学
色谱法
物理化学
物理
有机化学
复合材料
量子力学
作者
Nasrin Sultana,S. M. Abu Nayem,Abdul Awal,Mozammal Hoque,Md. Aminul Haque,Nafees Ahmed,Md. Abdul Aziz,A. J. Saleh Ahammad
标识
DOI:10.1002/slct.202402136
摘要
Abstract This study shows that incorporating taro carbon (TC) into a glassy carbon electrode (GCE) significantly enhanced surface charge transfer characteristics and conductivity and successfully separated the hydroquinone (HQ) and catechol (CT). Moreover, TC on the GCE surface reduced the overpotential of HQ and CT oxidation. Using X‐ray diffraction (XRD) analysis, field‐emission scanning electron microscopy (FESEM), and energy dispersive spectroscopy (EDS), the surface morphology and elemental composition of TC was investigated. The enhanced electron transfer process at TC‐GCE was studied using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) investigation. Scan rate analysis revealed that HQ and CT exhibited a higher oxidation affinity at TC‐GCE, with diffusion‐regulated anodic processes. Quantitative analysis showed a linear detection range of 5–200 μM for both HQ and CT, with LOD values of 0.47 μM for HQ and 0.51 μM for CT respectively. The modified electrode showed excellent selectivity, stability, and high recovery rates for detecting HQ and CT in tap water.
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