Advancing Zinc Anodes: Strategies for Enhanced Performance in Aqueous Zinc‐Ion Batteries

Abstract The promising features of aqueous zinc ion batteries (AZIBs), including their inherent safety, environmental friendliness, abundant raw materials, cost‐effectiveness, and simple manufacturing process, position them as strong candidates for large‐scale energy storage. However, their practical application faces significant challenges, such as uncontrolled dendritic growth, undesirable side reactions, and hydrogen evolution reactions (HER), which undermine the efficiency and longevity of the system. To address these issues, extensive research has been conducted to improve these batteries' energy density and lifespan. This comprehensive review explores the fundamental mechanisms of zinc dendrite formation, its properties, and the interfacial chemistry between the electrode and electrolyte. It also delves into strategies for protecting the zinc anode, with a focus on the modulation of zinc ion deposition dynamics at the electrolyte interface. The discussion concludes with an evaluation of the current challenges and future prospects of AZIB, aiming to enhance their viability for grid‐scale energy storage solutions.