化学
发光
荧光
配体(生物化学)
金属有机骨架
铕
发射强度
天线效应
金属
镧系元素
光化学
组合化学
分析化学(期刊)
物理化学
光电子学
色谱法
有机化学
生物化学
物理
受体
吸附
量子力学
离子
作者
Yingmin Jin,Wanpeng Ma,Bing Yan
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2022-01-07
卷期号:61 (3): 1349-1359
被引量:14
标识
DOI:10.1021/acs.inorgchem.1c02794
摘要
In this work, a novel luminescent hybrid material with double emission centers (Eu(TTA)0.2@9-1-UMOF) is successfully prepared, adopting a feasible design strategy. Initially, the second ligand 1,2,4-benzenetricarboxylic acid (H3BTC) is encapsulated based on a solid solution approach, which effectively improves the ligand-based emission intensity of the original LMOF and provides functional sites for introducing the second luminescent center; then, Eu3+ as the red emission source is loaded into the frameworks through a coordination post-synthetic modification method; finally, to balance the emission intensity at 613 nm (Eu3+) and 465 nm (1,4-naphthalenedicarboxylic acid (H2NDC)), 2-thenoyltrifluoroacetone (TTA) as a powerful antenna is introduced. Given the outstanding luminescence properties and structural stability of Eu(TTA)0.2@9-1-UMOF, it is further developed as a ratiometric sensor for detecting 1-hydroxypyrene (1-HP, the biomarker of polycyclic aromatic hydrocarbons (PAHs)) and Cu2+, which promotes the pre-diagnosis of human health. Notably, Eu(TTA)0.2@9-1-UMOF exhibits excellent selective recognition ability for both 1-HP and Cu2+ with high sensitivity (LOD = 4.06 × 10-6 mg/mL, 3.85 × 10-7 mol/L, respectively) and fast response speed. In addition, Eu(TTA)0.2@9-1-UMOF as a fluorescent probe shows great potential for the determination of 1-HP and Cu2+ in actual samples. More importantly, this work widens the road for the development of dual/multiple LMOF-based sensors for analytical applications.
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