化学
酰化
有机化学
溶剂
药物化学
氯化物
苯甲酰氯
作者
Xin Ge,Chao Qian,Xinzhi Chen
标识
DOI:10.1080/10426507.2012.702824
摘要
Abstract The acylation of some heterocyclic alcoholate anions with O,O-dialkyl phosphorochloridothioate has been investigated. Higher yields and fewer byproducts were achieved in water at 50 °C by employing an effective phase-transfer catalyst (PTC) (benzyl triethylammonium chloride [BTEAC]), acylation catalyst (AC) (4-dimethylaminopyridine), and surfactant (sodium dodecyl sulfate), under weakly basic (pH 9.5∼10) conditions. This reaction can also be applied to synthesize other insecticides with excellent yields.
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