X射线光电子能谱
析氧
钌
极化（电化学）
氧化物
热分解
腐蚀
分解
金属
阳极氧化
材料科学
氧气
无机化学
阳极
催化作用
电极
电化学
化学工程
氧化钌
化学
冶金
物理化学
生物化学
有机化学
工程类
作者
R. Kötz,H. J. Lewerenz,Samuel Stucki
摘要
Anodic oxidation of Ru and electrodes in has been investigated using x‐ray photoelectron spectroscopy. During evolution on Ru a highly defective hydrated oxide film is formed as a result of corrosion. At a temperature of 310°C in vacuum this film decomposes to metallic ruthenium. The surface of anodes prepared by thermal decomposition of contains some , which is stable during anodic polarization. A reaction path for evolution and corrosion on Ru and anodes is proposed.
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