Combined liquid‐crystalline polymers with chiral phases, 2. Lateral substituents

Abstract Chiral combined liquid‐crystalline polymers (i. e. polymers with the mesogenic groups in the main chain as well as in the side groups) with dipole moments perpendicular to the mesogenic groups were synthesized and characterized. These dipole moments were introduced by lateral substituents, which were located at different parts of the mesogen or directly at the chiral centre. The polymers, thus prepared, show crystalline or glassy phases at room temperature and smectic A, chiral smectic C * or cholesteric phases at higher temperatures. Since the lateral substituents decrease the melting temperature more strongly than the clearing temperature, the liquid‐crystalline phases are broadened compared to the unsubstituted polymers. Often glassy liquid‐crystalline phases are obtained. The dipole moments perpendicular to the mesogenic groups or at the chiral centre may help to obtain a high spontaneous polarisation in the chiral smectic C * phase (ferroelectricity).