High Performance of Thermoplastic Polyurethane-Graphene Oxide Self-Healing Composite Film

Graphene oxide (GO) sheets were dispersed into N, N-dimethylformamide (DMF) solution by ultrasonication and then mixed with thermoplastic polyurethane (TPU) solution uniformly, and further fabricated to GO-TPU film by casting process. The thermal properties, infrared photothermal response, and self-healing performance of the GO-TPU film were systematically investigated. The experimental results demonstrate that the thermal conductivity of GO-TPU film with 4 wt % GO and the initial concentration of 20 wt % TPU is 0.3719 W·m−1·K−1, which is 83.8% increase compared to pure TPU. The GO-TPU film has excellent infrared light-to-heat conversion efficiency. The infrared light-to-heat conversion efficiency of the GO-TPU film with 7 wt % GO and the initial concentration of 20 wt % TPU reaches the maximum, and the temperature increased by 63% compared to pure TPU, reaching 165.6 °C. The scratches on the GO-TPU composite film can be completely healed after being irradiated by infrared light for 10 min, which shows that the GO-TPU composite film has good self-healing properties.