Microstructure and Mechanical Properties of Porous Alumina Ceramics Fabricated by the Decomposition of Aluminum Hydroxide

The mechanical properties of Al 2 O 3 ‐based porous ceramics fabricated from pure Al 2 O 3 powder and the mixtures with Al(OH) 3 were investigated. The fracture strength of the porous Al 2 O 3 specimens sintered from the mixture was substantially higher than that of the pure Al 2 O 3 sintered specimens because of strong grain bonding that resulted from the fine Al 2 O 3 grains produced by the decomposition of Al(OH) 3 . However, the elastic modulus of the porous Al 2 O 3 specimens did not increase with the incorporation of Al(OH) 3 , so that the strain to failure of the porous Al 2 O 3 ceramics increased considerably, especially in the specimens with high porosity, because of the unique pore structures related to the large original Al(OH) 3 particles. Fracture toughness also increased with the addition of Al(OH) 3 in the specimens with higher porosity. However, fracture toughness did not improve in the specimens with lower porosity because of the fracture‐mode transition from intergranular, at higher porosity, to transgranular, at lower porosity.