Carbon–Phosphorus Bond Formation by Enantioselective Palladium‐Catalyzed Allylation of Diphenylphosphine Oxide

Abstract The enantioselective Pd‐catalyzed allylation of diaryl‐substituted allylic carbonates and diphenylphosphine oxide was investigated. This method gave allylic diphenylphosphine oxides in yields up to 95 % with 97 % ee. Pd‐catalyzed allylation of (E)‐methyl allyl carbonates with diisopropyl phosphonate was also examined.