缩水甘油
生物炼制
化学
甘油
有机化学
绿色化学
组合化学
生化工程
作者
Prisco Prete,Daniele Cespi,Fabrizio Passarini,Carmine Capacchione,Antonio Proto,Raffaele Cucciniello
标识
DOI:10.1016/j.cogsc.2022.100624
摘要
The synthesis of bio-based functional molecules and their further conversion to value-added products are among the most investigated research fields within the green chemistry community. In this work, we review the preparation of bio-based glycidol and its use as starting material for other chemicals. Herein, we discuss the catalytic approach for the synthesis of several classes of glycidol-derived organics characterized by relevant industrial applications. In detail, glycidol conversion to 1,2 and 1,3-propanediol, glycerol carbonate, solketal, monoalkyl glyceryl ethers and polymers is reported and future perspectives in this context are proposed. • Bio-based reaction pathways for glycidol preparation are reviewed. • Glycerochemistry as a valuable example of the 7th principle of green chemistry. • Glycidol conversion into value-added chemicals is discussed.
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