化学
结晶学
金属
水溶液中的金属离子
超分子化学
中子衍射
分子
硫系化合物
氧化物
氢氧化物
Crystal(编程语言)
单晶
配体(生物化学)
晶体结构
纳米技术
无机化学
有机化学
材料科学
受体
程序设计语言
生物化学
计算机科学
作者
А. В. Вировец,Eugenia V. Peresypkina,Manfred Scheer
出处
期刊:Chemical Reviews
[American Chemical Society]
日期:2021-10-27
卷期号:121 (23): 14485-14554
被引量:54
标识
DOI:10.1021/acs.chemrev.1c00503
摘要
The review presents a bird-eye view on the state of research in the field of giant nonbiological discrete metal complexes and ions of nanometer size, which are structurally characterized by means of single-crystal X-ray diffraction, using the crystal structure as a common key feature. The discussion is focused on the main structural features of the metal clusters, the clusters containing compact metal oxide/hydroxide/chalcogenide core, ligand-based metal-organic cages, and supramolecules as well as on the aspects related to the packing of the molecules or ions in the crystal and the methodological aspects of the single-crystal neutron and X-ray diffraction of these compounds.
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